MUSCLE. Multiple Sequence Alignment. Also has a nice web interface to submit jobs directly online

MAFFT. Multiple Sequence Alignment program for unix-like operating systems. Alternative to MUSCLE

t-coffee. Multiple Sequence Alignment. Alternative to MUSCLE

clustalW2. Multiple Sequence Alignment. Alternative to MUSCLE

MEGA. integrated tool for conducting sequence alignment, inferring phylogenetic trees, estimating divergence time. Fantastic GUI.

BioEdit Sequence Alignment Editor (for PC only) with various molecular evolution functions. Nice GUI. Use to be one of the leading program. Outdated (?) and no longer supported.

Most proprietary software (Sequencher, Geneious, CLC Genomics) will also permit multiple sequence alignments.